一种高增益多频带微带贴片单元的设计

设计了一种由圆、正八边形、矩形组合构成的微带贴片天线,其使用同轴线馈电。采用有限元法对所设计天线的电特性进行了仿真研究。同时也对天线在不同尺寸参数下的性能指标进行了对比分析。结果表明,天线兼具高增益和多频带的特性,在2.25~2.33GHz、3.51~3.7GHz、4.34~4.6GHz频带内,带内回波损耗全部小于-10d B,天线最高增益达到7.37d B,且天线的E面和H面辐射波束较好,半功率波束宽度约是60°;仿真结果证实了所设计的天线具有良好的性能指标。     

基于机电阻抗法的桁架结构加载状况监测

采用机电阻抗法监测三跨桁架结构加载状况,并利用BP神经网络方法进行结构载荷的定位和定量研究.首先,研究激励频率对压电陶瓷片感知结构变化的灵敏度的影响,并选取最佳敏感频段为190~200 k Hz.然后,测得2个监测节点独立性良好,有助于实现载荷定位监测.最后,将采集到的桁架结构加载时的部分阻抗虚部数据进行合理的数据压缩后作为输入样本.压缩前后的数据对比显示这种压缩方法具有可靠性.建立并训练神经网络,剩余部分数据经过相同处理后作为测试样本对训练好的BP网络进行测试.实验结果表明:基于机电阻抗法,利用神经网络可有效实现桁架结构中载荷的精确定位与定量.     

一种高频带利用率的PCSS-OFDM通信技术

为了提高扩频OFDM通信系统的频带利用率,提出了一种将并行组合扩频技术和OFDM技术相结合的并行组合扩频OFDM通信系统.对该系统进行了理论分析和建模仿真,并和频域扩频多载波CDMA系统进行了对比.结果表明,在高斯白噪声信道下,并行组合扩频OFDM系统不仅具有较高的频带利用率,而且在信噪比较大时可靠性优于频域扩频多载波CDMA系统;在多径衰落信道下,尽管并行组合扩频OFDM系统的可靠性比频域扩频多载波CDMA系统差,但是在一定程度上提高了系统频带利用率.     

各向异性砂土剪切带角度的理论分析

针对平面应变条件下各向异性砂土剪切带角度的试验规律,采用传统的3种理论和分叉理论进行对比分析。将平面应变条件下剪切带角度的试验结果按照传统3种理论整理发现,尽管传统3种理论可以估算同种砂剪切带角度的极小、中间和极大值,但无法解释其各向异性规律。砂土在平面应变条件下破坏时会产生明显的剪切带,当剪切带方向和砂土沉积面方向接近时,会较早诱发剪切带的产生,使材料强度降低,造成了平面应变条件下各向异性强度规律明显不同于常规三轴条件下的试验规律,采用分叉理论结合各向异性模型则可以有效解释这个规律。随砂土沉积面角度的变化,模型可以从细观角度解释常规三轴条件下剪切带角度的单调变化的试验规律,结合分叉理论可以描述平面应变条件下其先减小然后增大的规律。通过几种理论对比分析表明,模型结合分叉理论不但能够描述多种应力状态下的平面应变和常规三轴应力条件下剪切带角度表现的不同规律,而且能够从细观角度解释其各向异性成因。     

不同温度下AZ31镁合金绝热剪切变形局域化

为了了解镁合金在不同温度高应变率载荷作用下发生变形局域化的特点,进而揭示镁合金在高速冲击载荷作用下发生绝热剪切的特殊规律,采用分离式Hopkinson压杆对挤压态AZ31镁合金进行了常温及高温的高速冲击压缩试验,而后对不同温度冲击后的试样通过光学显微镜、扫描电镜和透射电镜进行变形机制的分析.结果表明:常温下试样在受到剪切力后,在剪切区的裂纹周围产生了大量的孪晶;高温下试样的剪切区内产生了明显的绝热剪切带,并且在剪切带周围发现了大量平行的孪晶.在TEM下观察到剪切带内为等轴晶晶粒,在剪切区内发生了动态再结晶过程.     

基于微缺陷累计成核数序列的岩石边坡滑移带尺度增长预测

岩石边坡滑移带是一个微损伤聚集带,每一个微损伤实际为一个微缺陷成核,因此,存在累计微缺陷成核数与滑移带尺度增长的对应关系.这个关系以裂纹系统的最大尺度cmax作为未知量,需要确定的参数有材料颗粒尺度δ,微裂纹尺-频分布分维数Dc,裂纹表面粗糙度分维数Ds,微裂纹总数Nd以及微缺陷成核累计数Nd.通过对边坡数值模拟微裂纹系统的统计分析,发现该尺度增长模型的预测值与实测值吻合较好.微缺陷成核数序列与声发射序列有较多的相似性,因此,研究结果为预测边坡内部裂纹增长提供了参考.     

燃烧过程中气体辐射特性分析

水蒸气、二氧化碳和一氧化碳是燃烧过程中的气体生成物,对燃烧系统内的辐射换热有重要影响。比较2个窄谱带数据库参数,即SoufianiTaine数据库和RiviereSoufiani数据库,针对参与性气体的非灰辐射特性,采用统计窄谱带模型考察水蒸气、二氧化碳和一氧化碳3种气体的光谱透射率。结果表明,基于RiviereSoufiani数据库的计算结果与逐线法基准解吻合较好,SoufianiTaine数据库偏差较大。引入离散坐标法,利用2个窄谱带数据库和统计窄谱带关联K模型,研究一维、二维和三维火焰的辐射换热情况,比较发现,采用2个数据库所得的辐射热流和辐射密度差别不大,仅在温度跃变处相差较大。     

Surface plasmon resonance-induced Ag-BaTiO3 composites for catalytic performance

Ferroelectric BaTiO₃ was combined with Ag nanoparticles for piezocatalytic and photocatalytic viewpoints. Microstructural characterization (X-ray diffraction and electron microscopy images) revealed that the Ag was successfully bounded with BaTiO₃. X-ray photoelectron spectrum also confirmed the presence of Ag. Further, its performance was examined for dye degradation under visible light (for photocatalysis) and ultrasonication (for piezocatalysis). In both the catalysis processes, there was a significant improvement in Ag-loaded BaTiO₃ sample-based catalytic reactions. Catalytic performance was evaluated for multiple cycles and was found consistent. Scavenger tests were also performed to understand catalytic reactions.     

Broadband excited Na3Tb(PO4)2:Ce3+/Eu2+ green/yellow-emitting phosphors with high color purity for LED-based application

To enhance the display quality of light-emitting diodes (LEDs), it is of great significance to exploit green/yellow-emitting phosphors with narrow emission band, high quantum yield, and excellent color purity to satisfy the application. Herein, orthophosphate-based green/yellow-emitting Na₃Tb(PO₄)₂:Ce³⁺/Eu²⁺ (NTPO:Ce³⁺/Eu²⁺) phosphors have been successfully synthesized by a facile solid-state reaction method. The absorption band of NTPO samples was extended to the near-ultraviolet region and the absorption efficiency was significantly improved owing to a highly efficient energy transfer from Ce³⁺/Eu²⁺ ion to Tb³⁺ ion in NTPO host certified by time-resolved PL spectra. Upon 300 nm excitation, the NTPO:Ce³⁺ is characterized by ultra-narrow-band green emission of Tb³⁺ with an absolute quantum yield of 94.5%. Unexpectedly, NTPO:Eu²⁺ emits bright yellow light with a color purity of 73% as a result of the blending of green light emission from Tb³⁺ and red light emission from Eu³⁺. The thermal stability has been improved by controlling the stoichiometric ratio of Na⁺. The prototype white LED used yellow-emitting NTPO:Eu²⁺ phosphor has higher color-rendering index (Ra = 83.5), lower correlated color temperature (CCT = 5206 K), and closer CIE color coordinates (0.338, 0.3187) to the standard white point at (0.333, 0.333) than that used green-emitting NTPO:Ce³⁺ phosphor, indicating the addition of the yellow light component improved the Ra of the trichromatic (RGB) materials.     

Tuning fermi level and band gap in Li4Ti5O12 by doping and vacancy for ultrafast Li+ insertion/extraction

Li₄T_i5O₁₂ (LTO) attracts great interest due to the “zero strain” during cycles but the poor electronic and ionic conductivity critically impede the practical application. Herein, we report a synergy strategy of tuning localized electrons to shift Fermi level and band gap by Mg/Zr co-doping and oxygen vacancy incorporation, which significantly improves Li⁺ and electronic transport. More importantly, the intrinsic synergistic mechanism has been revealed by neutron diffraction, X-ray absorption spectra, and first-principles calculations. The “elastic effect” of lattice induced by Mg/Zr co-doping allows LTO to accommodate more oxygen vacancies to a certain degree without a severe lattice distortion, which largely improves the electronic conductivity. Mg/Zr co-doping and oxygen vacancy incorporation effectively enhanced the dynamic characteristics of LTO electrode, achieving the excellent rate performance (90 mAh/g at 20C) and cycle stability (96.9% after 500 cycles at 10C). First-principles calculations confirm Fermi level shifts to the conduction band, and the band gap becomes narrowed due to the synergistic modulation, and the intrinsic mechanism of the enhanced electronic and Li-ion conductivity is clarified. This study offers some insights into achieving the fast Li⁺ insertion/extraction by tuning the crystal and electronic structure with lattice doping and oxygen vacancy engineering.